Periodic mesoporous phenylenesilicas with ether or sulfide hinge groups—a new class of PMOs with ligand channels?

Chemical Communications Pub Date: 2004-09-23 DOI: 10.1039/B410397A

Abstract

A new class of periodic mesoporous organosilicas (PMOs) with 4-phenyl ether and 4-phenyl sulfide bridge-bonded silsesquioxanes integrated into the pore walls to create ligand channels have been synthesized using inorganic salt-assisted self-assembly directed by a supramolecular polyoxyethylene (10) stearyl ether (Brij 76) template.

Graphical abstract: Periodic mesoporous phenylenesilicas with ether or sulfide hinge groups—a new class of PMOs with ligand channels
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