Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions?
Dalton Transactions Pub Date: 2018-07-16 DOI: 10.1039/C8DT02462F
Abstract
The bis(di-tert-butyl-aminophenyl)amine ligand H3LN,N,N was reacted with Mn(II), Co(II), Fe(III) and Cu(II) salts in air. The ligand undergoes oxidative transformations, which involve intra and intermolecular C–N and N–N bond formations. A rare aromatic C–N bond cleavage leading to a C–O bond has also been observed.
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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