Redox-active ligand based Mn(i)-catalyst for hydrosilylative ester reduction?
Chemical Communications Pub Date: 2021-11-03 DOI: 10.1039/D1CC05614J
Abstract
Herein a Mn(I) catalyst bearing a redox-active phenalenyl (PLY) based ligand is reported for the efficient hydrosilylation of esters to alcohols using the inexpensive silane source polymethylhydrosiloxane (PMHS) under mild conditions. Mechanistic investigations suggest a strong ligand–metal cooperation where a ligand-based single electron transfer (SET) process initiates the reaction through Si–H bond activation.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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