Solvent effect on hierarchical assembly of 2-aminooctane-functionalized naphthalenediimide?
RSC Advances Pub Date: 2013-12-19 DOI: 10.1039/C3RA45372C
Abstract
Hierarchical assembly of 2-aminooctane-functionalized naphthalenediimide (NDI) was investigated via a solvent displacement method. That is, a good solvent (ethyl acetate) of NDI was fast dispersed into a poor solvent (methanol, methanol + water, or water). The NDI assemblies with varied scale, shape, and aggregation were formed and fully characterized by SEM, TEM, EDX, UV-vis, and fluorescence. The results demonstrated that the use of a mixture of two poor solvents can provide fine-tuning of intermolecular interactions. In addition, to reveal the structure–property correlation, the I–V characteristics of the as-obtained NDI architectures were explored.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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