Organometallic macromolecules with piano stool coordination repeating units: chain configuration and stimulated solution behaviour?

Chemical Communications Pub Date: 2014-07-10 DOI: 10.1039/C4CC03064H

Abstract

Theoretical calculations illustrate that organometallic macromolecules with piano stool coordination repeating units (Fe-acyl complex) adopt linear chain configuration with a P–Fe–C backbone surrounded by aromatic groups. The macromolecules show molecular weight-dependent and temperature stimulated solution behaviour in DMSO.

Graphical abstract: Organometallic macromolecules with piano stool coordination repeating units: chain configuration and stimulated solution behaviour
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