Selective aerobic oxidation of halides and amines with an inorganic-ligand supported zinc catalyst?

Dalton Transactions Pub Date: 2018-09-05 DOI: 10.1039/C8DT03003K

Abstract

A practical, efficient and environmentally benign catalytic protocol for the oxidative cross-coupling reaction of halides with amines, oxidative self-coupling of amines and oxidation of halides was developed with inorganic-ligand supported ZnPOM (NH4)4[ZnMo6O18(OH)6] using molecular oxygen. This method mainly utilizes an inorganic polymolybdate ligand to support the Zn2+ ion, avoiding the use of complicated organic ligands.

Graphical abstract: Selective aerobic oxidation of halides and amines with an inorganic-ligand supported zinc catalyst
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