Organic synthesis of fixed CO2 using nitrogen as a nucleophilic center
Organic & Biomolecular Chemistry Pub Date: 2020-08-25 DOI: 10.1039/D0OB01590C
Abstract
In this review, recent progress in the application of CO2 as an electrophilic reagent and nitrogen as a nucleophilic center under different catalytic conditions in organic synthesis is summarized. The used catalytic methods in the reactions of CO2 and nitrogen are classified as metal catalysis, metal-free catalysis, photocatalysis and electrocatalysis. Various catalytic conditions have been used to solve the problems of thermodynamic properties and stability of CO2. The transformation mechanisms of these reactions are discussed.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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