Salen-based hypercrosslinked polymer-supported Pd as an efficient and recyclable catalyst for C–H halogenation?

Chemical Communications Pub Date: 2020-01-30 DOI: 10.1039/C9CC09781C

Abstract

In this work, we report the first use of a salen-based hypercrosslinked polymer-supported Pd catalyst to carry out C–H halogenation. This catalyst can effectively catalyze C–H bromination and chlorination even better than its homogeneous counterpart Pd(OAc)2. It also showed excellent reusability without loss of catalytic activity for ten cycles. A broad substrate scope was explored and moderate to excellent yields were obtained.

Graphical abstract: Salen-based hypercrosslinked polymer-supported Pd as an efficient and recyclable catalyst for C–H halogenation
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