Reactivity of the tetraphenyldithioimidodiphosphine–diiodine (HL·I2) adduct towards indium powder
Dalton Transactions Pub Date: 2003-03-11 DOI: 10.1039/B211542E
Abstract
The reaction of indium powder with the mixture (SPPh2)2NH and I2
(HL·I2) in Et2O at room temperature gave the indium(III) complex InLI2
(1). The reaction occurs in two steps, the first of which leads to the formation of InI3 and free HL, then the subsequent reaction between these species yields compound 1, H+, and the anion InI4?. The crystal lattice of 1 is made up of neutral acentric molecules where the metal ion is bonded through two sulfur atoms to one anionic (SPPh2)2N?
(L)
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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