Ruthenium/base-catalyzed ortho-selective C–H arylation of acylarenes with halogenated arylboronates?

RSC Advances Pub Date: 2015-12-03 DOI: 10.1039/C5RA19810K

Abstract

Ruthenium-catalyzed ortho-selective C–H arylation of acylarenes with halogenated aryl-boronates was promoted by the catalytic amount of bases and provided desired halogenated biaryls in excellent yields under 0.2–1 mol% ruthenium catalyst loading.

Graphical abstract: Ruthenium/base-catalyzed ortho-selective C–H arylation of acylarenes with halogenated arylboronates
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