Reaction of tetracyanoethylene with SCl2: new molecular rearrangements
Chemical Communications Pub Date: 2000-02-10 DOI: 10.1039/A909307I
Abstract
The chloride ion catalysed addition of SCl2 to TCNE gives the dicyanomethylene-1,2,6-thiadiazine 3 as major product together with two unexpected minor products, pyrimidine 4 and pyrroloimidazothiadiazine 5, whose X-ray crystal structures are described; the products are derived from interaction of SCl2 with one cyano group with neighbouring group participation by two others.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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