One-dimensional Cu(II) coordination polymers: tuning the structure by modulating the “carboxylate arm” lengths of polycarboxylate ligands?

CrystEngComm Pub Date: 2009-02-13 DOI: 10.1039/B820834D

Abstract

To understand the influence of the ligand on crystal growth, two new polycarboxylate ligands, 2-(carboxyphenyl)iminoacetic propanoic acid (H3cpiap) and 2-(carboxyphenyl)iminodipropanoic acid (H3cpidp), have been synthesized. The reaction of each with Cu(NO3)2·3H2O under similar reaction conditions yields two 1D coordination polymers {[Cu3(cpiap)2(H2O)3](μ-H2O)}n·7nH2O (1) and [Cu(H2cpidp)2(H2O)2]n·4nH2O (2), respectively. A T5(2) 1D water tape constructed from an edge-sharing cyclic pentamer has been observed in compound 1, in which the water chains interact with the 1D coordination polymer chains to form a 3D supramolecular binodal (5,8)-network through hydrogen-bonding interactions.

Graphical abstract: One-dimensional Cu(II) coordination polymers: tuning the structure by modulating the “carboxylate arm” lengths of polycarboxylate ligands
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