Photocatalyzed cross-dehydrogenative coupling of silanes with alcohols and water?
Chemical Communications Pub Date: 2021-03-05 DOI: 10.1039/D1CC00129A
Abstract
An efficient method for the dehydrogenative coupling of silanes with alcohols under photocatalysis was developed. The reaction proceeded in the presence of Ru(bpy)3Cl2 (0.5 mol%) under visible light irradiation in acetonitrile at room temperature. The developed methodology was also applicable for the synthesis of silanols using water as a coupling partner.
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Journal Name:Chemical Communications
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CAS no.: 89640-58-4