Selective production of glycols from xylitol over Ru on covalent triazine frameworks – suppressing decarbonylation reactions?
Green Chemistry Pub Date: 2018-02-23 DOI: 10.1039/C8GC00208H
Abstract
Ru on covaltent triazine frameworks (CTF) are highly active and selective catalysts for the conversion of xylitol to glycols (80% C-yield) in basic media. With increasing N-content decarbonylation reactions are suppressed leading to high glycol selectivity. The suppression can be attributed to the presence of N in the support and to metal-support interactions. The catalysts exhibit high stability and could be recycled 5 times with minor loss of activity.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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