Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides??
Chemical Communications Pub Date: 2014-05-14 DOI: 10.1039/C4CC02601B
Abstract
The reaction of the 17e nickel(I) radical [CpNi(IDipp)] (1, IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with P4 results in a nickel tetraphosphide [{CpNi(IDipp)}2(μ-η1:η1-P4)] with a butterfly-P42? ligand; related chalcogenides [{CpNi(IDipp)}2(μ-E2)] (E = S, Se, Te) and [{CpNi(IDipp)}2(μ-E3)] (E = S, Se) are formed with S8, Se∞ and Te∞.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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