Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals?
Chemical Communications Pub Date: 2015-01-27 DOI: 10.1039/C4CC09850A
Abstract
This work describes the design and application of a single-pot, reductive arene C–H silanolization of aromatic esters for synthesis of ortho-formyl arylsilanols. This strategy involves a sequence of two transition metal (Ir and Rh)-catalyzed reactions for reductive arene ortho-silylation directed by hydridosilyl acetals and hydrolysis.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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