Ni-catalyzed reductive coupling of α-halocarbonyl derivatives with vinyl bromides?
Organic & Biomolecular Chemistry Pub Date: 2016-11-15 DOI: 10.1039/C6OB02269C
Abstract
This work describes the vinylation of α-halo carbonyl compounds with vinyl bromides under Ni-catalyzed reductive coupling conditions. While aryl-conjugated vinyl bromides entail pyridine as the sole labile ligand, the alkyl-substituted vinyl bromides require both bipyridine and pyridine as the co-ligands.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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