Novel formation of a phenylated isoquinolino[3′,4′:1,2][60]fullerene
Chemical Communications Pub Date: 1900-01-01 DOI: 10.1039/A707430A
Abstract
Reaction of C60Ph5Cl with cyanogen bromide results in replacement of the chlorine by BrCN and ring closure between the addend and an adjacent phenyl ring, giving a 1-bromoisoquinoline derivative of [60]fullerene; this readily undergoes nucleophilic replacement of Br by OH to give the corresponding 1-isoquinolone derivative.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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