Palladium-catalyzed enantioselective carboannulation of 1,3-dienes with aryl iodides enables access to chiral indanes?
Chemical Communications Pub Date: 2018-07-31 DOI: 10.1039/C8CC04641G
Abstract
A palladium-catalyzed enantioselective carboannulation of 1,3-dienes and aryl iodides has been established by using a BINOL-based phosphoramidite ligand. This reaction proceeded via a tandem Heck-type insertion and asymmetric intramolecular Tsuji–Trost allylic alkylation, providing indane derivatives with high levels of enantioselectivity (up to >99% ee).
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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