Reaction of alkenecarboxylic acids with isocyanates via rhodium(iii)-catalyzed C–H activation: a versatile route to cyclic imides?
Organic Chemistry Frontiers Pub Date: 2016-06-13 DOI: 10.1039/C6QO00119J
Abstract
Under rhodium(III) catalysis, substituted propenoic acids successfully reacted with aryl isocyanates to provide cyclic imides via direct functionalization of the β-alkenyl C–H bond followed by intramolecular cyclization. The cascade process has been corroborated by the isolated intermediate. The reaction provides direct access to cyclic imides from readily available starting materials.
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Journal Name：Organic Chemistry Frontiers
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CAS no.: 89640-58-4
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