N-Chlorosuccinimide-promoted synthesis of thiophosphates from thiols and phosphonates under mild conditions?
Green Chemistry Pub Date: 2013-10-28 DOI: 10.1039/C3GC41839A
Abstract
A very simple N-chlorosuccinimide-promoted synthesis of thiophosphates through the coupling of thiols and phosphonates is reported. Notably, the reactions were carried out in the absence of a base. Functional groups including fluoro, bromo and trifluoromethyl are all tolerated by the reaction conditions employed. Both aryl and alkyl thiols are coupled smoothly with a broad spectrum of phosphonates to afford the corresponding thiophosphates in good to excellent yields.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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