3D supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules?
Chemical Communications Pub Date: 2018-06-13 DOI: 10.1039/C8CC04079F
Abstract
A clickable fullerene hexa-adduct scaffold has been functionalized with twelve triarylamine subunits. The light-triggered self-assembly of this molecular unit leads to 3D honeycomb-like structures with inner pores of around 10 nm diameter. Multiple grafting of triarylamine subunits onto a hard-core C60 unit increases the dimensionality of the self-assembly process by reticulating the 1D nanowires typically obtained from the supramolecular polymerization of triarylamine monomers.
![Graphical abstract: 3D supramolecular self-assembly of [60]fullerene hexaadducts decorated with triarylamine molecules](http://scimg.chem960.com/usr/1/C8CC04079F.jpg)
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Journal Name：Chemical Communications
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