New insights into the mechanical and self-healing properties of polymers cross-linked by Fe(iii)-2,6-pyridinedicarboxamide coordination complexes?

Polymer Chemistry Pub Date: 2018-11-29 DOI: 10.1039/C8PY01233D

Abstract

In order to understand the mechanical and self-healing properties of polymers cross-linked by Fe(III)-2,6-pyridinedicarboxamide (pdca) coordination complexes, herein we performed the reaction between 2,6-pyridinedicarboxamide and FeCl3 under both neutral and alkaline conditions, and studied the dynamic ligand exchange properties of the resulting model complexes. The results showed that [Fe(Hpdca)]+ exhibited a rapid ligand exchange property which was not observed for [Fe(pdca)]?. Correspondingly, polymer Fe-Hpdca-PBCA (PBCA = poly(butadiene-co-acrylonitrile)) was weak, highly stretchable and self-healable, while Fe-pdca-PBCA was strong and poorly stretchable and can only be partially healed with a prolonged time. These results deliver a clear indication of the important impact of the bond strength and dynamics of coordination complexes on the mechanical and self-healing properties of polymers. Such an understanding is helpful for further design of novel synthetic polymers which can achieve an optimal balance between the mechanical strength and self-healing performance.

Graphical abstract: New insights into the mechanical and self-healing properties of polymers cross-linked by Fe(iii)-2,6-pyridinedicarboxamide coordination complexes
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