Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine?
Chemical Communications Pub Date: 2012-03-27 DOI: 10.1039/C2CC31234D
Abstract
The dimetallic [M2(bpy)2(NO3)2](NO3)2 moieties (M = Pd(II) or Pt(II)) react preferentially at the pyrazolyl end of the pyridyl-pyrazole ligand, giving rise to dimetallic corners. Subsequently, the dimetallic corner building blocks featuring two pyridine donors are coordinated by monometallic [M(bpy)(NO3)2] moieties (M = Pd(II) or Pt(II)) to form homo- or hetero-metallomacrocycles.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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