Photolysis of perfluoroazooctane in an argon matrix

Physical Chemistry Chemical Physics Pub Date: 2000-05-11 DOI: 10.1039/B000851F

Abstract

The photodissociation mechanism of perfluoroazooctane was investigated using a matrix isolation technique on the basis of IR and EPR spectra and MO calculation. The detection and identification of perfluorooctyl diazenyl radical show that it is a feasible photolytic intermediate of the decomposition of perfluoroazooctane.

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