Novel ruthenium–pyridinedicarboxylate complexes of terpyridine and chiral bis(oxazolinyl)pyridine: a new catalytic system for alkene epoxidation with [bis(acetoxy)iodo]benzene as an oxygen donor
Chemical Communications Pub Date: 1900-01-01 DOI: 10.1039/A705109C
Abstract
Ruthenium–pyridine-2,6-dicarboxylate (pydic) complexes 1–3 of terpyridine and chiral bis(oxazolinyl)pyridines (pybox-ip and pybox-ph), which can be synthesized from [Ru(p-cymene)Cl2]2 and the corresponding ligands, exhibit catalytic activity for epoxidation of trans-stilbene in combination with [bis(acetoxy)iodo]benzene: asymmetric induction with 2 was observed in 74% ee for trans-stilbene.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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