Pd/Xiang-Phos-catalyzed enantioselective intermolecular carboheterofunctionalization of norbornene and norbornadiene?
Chemical Communications Pub Date: 2020-09-18 DOI: 10.1039/D0CC04996D
Abstract
A highly enantioselective Pd/Xiang-Phos-catalyzed carbohetero-functionalization of norbornene is described, giving a direct access to various chiral norbornane-fused dihydrofurans and dihydro-pyrroles. This synthetic methodology provides the first example of asymmetric carboetherification of norbornene, and also tolerates norbornadiene well.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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