Mn2+ cation-directed ionothermal synthesis of an open-framework fluorinated aluminium phosphite–phosphate?

RSC Advances Pub Date: 2014-06-24 DOI: 10.1039/C4RA05350H

Abstract

An open-framework fluorinated aluminium phosphite–phosphate, H3.2Mn3.4[C6N2H11]2{Al12(HPO3)15.0(HPO4)3.0F12}·14H2O (DNL-2), was ionothermally synthesized by employing the in situ released Mn2+ cations as structure-directing agent.

Graphical abstract: Mn2+ cation-directed ionothermal synthesis of an open-framework fluorinated aluminium phosphite–phosphate
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