Palladium mediated one-pot synthesis of 3-aryl-cyclohexenones and 1,5-diketones from allyl alcohols and aryl ketones??
Organic & Biomolecular Chemistry Pub Date: 2021-01-13 DOI: 10.1039/D0OB02515A
Abstract
One-pot synthesis of Robinson annulated 3-aryl-cyclohexenones from allyl alcohols and ketones using palladium is reported. Long chain aliphatic or aryl substitutions at the C1 position of allyl alcohol result in the formation of 1,5-diketone products. This simple one-pot method avoids the use of highly electrophilic vinyl ketones.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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