A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines?
Chemical Communications Pub Date: 2019-04-18 DOI: 10.1039/C9CC01947B
Abstract
We report a new mono-armed pillar[5]arene with the amino-substituent self-included in the pillarene cavity, which can stabilize the hemiaminals and imines formed from the reaction of aliphatic amines and aldehydes as monitored by mass spectroscopy.
![Graphical abstract: A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines](http://scimg.chem960.com/usr/1/C9CC01947B.jpg)
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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