meso-Tetrakis[o-(N-methyl)pyridinium]porphyrin ensembles with axially coordinated cyclodextrin-penetrating phenethylimidazole: reversible dioxygen-binding in aqueous DMF solution
Chemical Communications Pub Date: 2002-11-21 DOI: 10.1039/B208882G
Abstract
α-Cyclodextrin (αCD)-penetrating 2-methyl-1-phenethylimidazole coordinates to the zinc(II) and iron(II) complexes of meso-tetrakis[o-(N-methyl)pyridinium] porphyrinate, giving non-covalently linked αCD-porphyrin ensembles; the iron(II) complex can reversibly bind and release dioxygen in aqueous DMF solution.
![Graphical abstract: meso-Tetrakis[o-(N-methyl)pyridinium]porphyrin ensembles with axially coordinated cyclodextrin-penetrating phenethylimidazole: reversible dioxygen-binding in aqueous DMF solution](http://scimg.chem960.com/usr/1/B208882G.jpg)
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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