Polymerization of an optically active phenylacetylene derivative bearing an azide residue by click reaction and reaction with a rhodium catalyst?

Chemical Communications Pub Date: 2008-06-06 DOI: 10.1039/B806343E

Abstract

A facile method for synthesizing diverse optically active polymers with different backbone structures was developed by the polymerization of an optically active aromatic azide bearing an acetylene unit with a rhodium catalyst followed by the click reaction of the pendant azides or by the click polymerization of the monomer.

Graphical abstract: Polymerization of an optically active phenylacetylene derivative bearing an azide residue by click reaction and reaction with a rhodium catalyst
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