Mechanism of C–P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere?
Chemical Communications Pub Date: 2019-11-25 DOI: 10.1039/C9CC07923H
Abstract
We report on the basis of DFT computations a plausible and detailed reaction mechanism for the first Pd-catalyzed decarbonylative phosphorylation of amides forming C–P bonds, which reveals, among other things, crucial events in the second coordination sphere, including ion pair and hydrogen bonding interactions as well as proton transfer.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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