Palladium-catalyzed synthesis of monofluoroalkenes from 3,3-difluoropropenes using dimethylmalonate and derivatives as nucleophiles?
Organic & Biomolecular Chemistry Pub Date: 2017-02-28 DOI: 10.1039/C7OB00376E
Abstract
The synthesis of monofluoroalkenes bearing a malonate or its derivatives at the β position is presented. The reaction can be performed with various 3,3-difluoropropenes. A preliminary result for an enantioselective variant is also reported. Further synthetic transformations of a monofluoroalkene were also accomplished.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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