Poly(ethylene glycol) dimethyl ether mediated oxidative scission of aromatic olefins to carbonyl compounds by molecular oxygen?
RSC Advances Pub Date: 2021-04-14 DOI: 10.1039/D1RA02007B
Abstract
A simple, and practical oxidative scission of aromatic olefins to carbonyl compounds using O2 as the sole oxidant with poly(ethylene glycol) dimethyl ether as a benign solvent has been developed. A wide range of monosubstituted, gem-disubstituted, 1,2-disubstituted, trisubstituted and tetrasubstituted aromatic olefins was successfully converted into the corresponding aldehydes and ketones in excellent yields even with gram–scale reaction. Some control experiments were also conducted to support a possible reaction pathway.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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