Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water?
Green Chemistry Pub Date: 2017-02-16 DOI: 10.1039/C7GC00212B
Abstract
A metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N,N,N-trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereoselective product was formed.
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Journal Name：Green Chemistry
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CAS no.: 89640-58-4
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