On the relative migratory aptitudes of carbon and heteroatoms in borate complexes. A surprising α-thia effect

Chemical Communications Pub Date: 2004-02-27 DOI: 10.1039/B311292F

Abstract

Dimethylsulfoxonium methylide reacts with dicyclohexyl(α-thiophenylmethyl)methylborane via 1,2-alkyl migration and alkyldithiaborolane via 1,2-sulfur migration.

Graphical abstract: On the relative migratory aptitudes of carbon and heteroatoms in borate complexes. A surprising α-thia effect
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