Palladium nanoparticles generated in situ used as catalysts in carbonylative cross-coupling in aqueous medium?
RSC Advances Pub Date: 2016-04-04 DOI: 10.1039/C6RA02889F
Abstract
Pd NPs, obtained in situ from imidazole complexes Pd(im)2Cl2 (im = methylimidazole, butylimidazole), efficiently catalyze the carbonylative Suzuki coupling in water at 80 °C and 1 atm of CO. In the catalytic system, used without any additional ligands, differently substituted diaryl ketones were obtained with yields of up to 100% in 1 h. Under slightly modified conditions, Pd NPs catalyze the alkoxycarbonylation of iodobenzenes to esters with high yield.
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Journal Name：RSC Advances
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CAS no.: 89640-58-4
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