Novel carbon nanofiber-supported Ni(0) nanoparticles catalyse the Heck reaction under ligand-free conditions?

RSC Advances Pub Date: 2016-03-02 DOI: 10.1039/C6RA01918H

Abstract

Nickel, as an inexpensive and abundant transition metal, is widely used in the field of catalysis. A novel one-dimensional carbon nanofiber-supported Ni(0) composite catalyst (Ni(0)/CNFs) was prepared in this work, and its catalytic properties in the Heck reaction were explored. Compared with conventional nickel–ligand catalyst systems, the solid Ni(0)/CNFs composite catalyst has unique advantages. Ni(0)/CNFs does not require ligands or complexes, which results in high efficiency and is beneficial for reuse in the Heck reaction.

Graphical abstract: Novel carbon nanofiber-supported Ni(0) nanoparticles catalyse the Heck reaction under ligand-free conditions
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