Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: an effective [TeFe3(CO)9]2? ligand?
Dalton Transactions Pub Date: 2015-08-25 DOI: 10.1039/C5DT03242C
Abstract
A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9]2? and NHCs as the ligands, these di-Cu(I)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).
![Graphical abstract: Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: an effective [TeFe3(CO)9]2? ligand](http://scimg.chem960.com/usr/1/C5DT03242C.jpg)
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Journal Name：Dalton Transactions
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CAS no.: 89640-58-4
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