Non-covalent functionalization of carbon nanotubes with boronic acids for the wiring of glycosylated redox enzymes in oxygen-reducing biocathodes?
Journal of Materials Chemistry B Pub Date: 2014-02-19 DOI: 10.1039/C3TB21846E
Abstract
We report the non-covalent functionalization of multiwalled carbon nanotubes with pyrene monomers bearing a boronic acid function. These functionalized electrodes were used to wire horseradish peroxidase via formation of a covalent boronic ester bond under mild conditions with the glycosylated enzyme. By attaching glucose oxidase at the same time, a bi-enzymatic system was elaborated and showed efficient bioelectrocatalytic oxygen reduction under physiological conditions.
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Journal Name：Journal of Materials Chemistry B
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CAS no.: 89640-58-4
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