A novel route for preparing highly proton conductive membrane materials with metal-organic frameworks?

Chemical Communications Pub Date: 2012-10-16 DOI: 10.1039/C2CC37045J

Abstract

Fe-MIL-101-NH2 was prepared by a novel method. The MOFs adhered well to SPPO via chemical bonds, and yielded the mixed-matrix Fe-MIL-101-NH2-SPPO membrane for use in fuel cells. The proton conductivity of the membranes was as high as 0.10 S cm?1 at room temperature and 0.25 S cm?1 at 90 °C.

Graphical abstract: A novel route for preparing highly proton conductive membrane materials with metal-organic frameworks
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