Neodymium(iii) d(–)-citramalate: a chiral three-dimensional framework with water-filled channels

CrystEngComm Pub Date: 2007-04-19 DOI: 10.1039/B703230G

Abstract

Reaction of neodymium nitrate with enantiopure D(–)-citramalic acid (H3citml) in the presence of NaOH under hydrothermal conditions gave the complex {[Nd7(Hcitml)8(NO3)(H2O)8](CO3)2·4H2O}n, which crystallizes as a three-dimensional framework with a complex hexagonal network of channels.

Graphical abstract: Neodymium(iii) d(–)-citramalate: a chiral three-dimensional framework with water-filled channels
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