Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides?
Organic & Biomolecular Chemistry Pub Date: 2017-11-27 DOI: 10.1039/C7OB02620J
Abstract
A new protocol for achieving the phosphination of arenes, arenols and thiols has been disclosed. This chemistry, in which diaryl(((trifluoromethyl)sulfonyl)oxy)phosphines as a kind of electrophilic phosphination reagents are in situ generated from diarylphosphine oxides, provides an efficient and mild approach for the synthesis of aromatic organophosphorus compounds.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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