Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process?
Organic Chemistry Frontiers Pub Date: 2018-08-07 DOI: 10.1039/C8QO00661J
Abstract
The first example of a metal- and reductant-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process is reported. In this reaction, sodium sulfinates play dual roles of a sulfonylation reagent and activating agent. This procedure is expected to complement the current methods for the radical reaction of quinoline N-oxides.
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Journal Name：Organic Chemistry Frontiers
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CAS no.: 89640-58-4
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