Metal-free arylation of pyrimidines through a photochemical process?
Chemical Communications Pub Date: 2015-12-16 DOI: 10.1039/C5CC08927A
Abstract
Pyrimidinyl and pyrazinyl radicals were generated under moderate energetic irradiation conditions (UVA), and proved to be prompt to undergo C–C bond formation processes. Hetero-biaryl derivatives were obtained in good to high yields with highly interesting functional group selectivities. Bis hetero-biaryls were also easily accessible leading to original compounds, ready for further transformations. Experiments supporting radical processes have been reported.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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