MeOTf/KI-catalyzed efficient synthesis of 2-arylnaphthalenes via cyclodimerization of styrene oxides?
Organic & Biomolecular Chemistry Pub Date: 2021-09-24 DOI: 10.1039/D1OB01619A
Abstract
The MeOTf/KI-catalyzed synthesis of 2-arylnaphthalene derivatives from aryl ethylene oxides in alcohol under ambient conditions is described. The present protocol has a higher atom efficiency and wider substrate applicability with excellent yields. The reaction proceeded using the aryl ethylene oxides to give 2-arylnaphthalenes either in homo-coupling or in cross-coupling. The reaction could also be carried out at the gram scale in minutes.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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