Molecular-level insights into the self-assembly driven enantioselective recognition process?
Chemical Communications Pub Date: 2020-12-22 DOI: 10.1039/D0CC06612E
Abstract
The importance of the orientation of functional groups in a chiral environment on enantioselective recognition has been demonstrated. Orientation controlled interactions of functional groups in (R)/(S)-MA lead to a visually differentiable morphology with an arginine-based gelator. The crucial role of various molecular–level interactions discriminating the enantioselective self-assembly has been established using different analytical techniques, crystal structure analysis, and DFT calculations.
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Journal Name:Chemical Communications
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CAS no.: 89640-58-4