Nano-γ-Al2O3/SbCl5: an efficient catalyst for the synthesis of 2,3-dihydroperimidines?

RSC Advances Pub Date: 2018-02-07 DOI: 10.1039/C7RA13593A

Abstract

Nano-γ-Al2O3/SbCl5 as a new Lewis acid nano catalyst was synthesized and characterized by FTIR, XRD, FESEM, TEM, EDS, BET and TGA techniques. Nano-γ-Al2O3/SbCl5 has been employed for synthesis of 2-substituted perimidines via reaction of naphthalene-1,8-diamine with various aldehydes at room temperature under solvent-free conditions. This protocol proffers several benefits including high yields, easy workup, short reaction times and simple reaction conditions.

Graphical abstract: Nano-γ-Al2O3/SbCl5: an efficient catalyst for the synthesis of 2,3-dihydroperimidines
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