A novel three-dimensional heterometallic compound: templated assembly of the unprecedented planar “Na?[Cu4]” metalloporphyrin-like subunits?

Chemical Communications Pub Date: 2007-02-21 DOI: 10.1039/B618296H

Abstract

A 3D heterometallic compound, [Cu4Na4(TzDC)4(H2O)7]n (H3TzDC = 1,2,3-triazole-4,5-dicarboxylic acid), which contains unprecedented planar “Na?[Cu4]” metalloporphyrin-like subunits, was synthesized by hydrothermal reactions involving in situ formation of the ligand and templated assembly of the metalloporphyrin-like subunits.

Graphical abstract: A novel three-dimensional heterometallic compound: templated assembly of the unprecedented planar “Na?[Cu4]” metalloporphyrin-like subunits
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